Yep, everything works any where OpenLP works.
To export songs go to file>export>songs then to copy the files to your Windows machine and go to file>import>songs
I'm unsure how to do bibles since I don't use that feature.
be aware when importing song select stuff, in my experience then you may need to correct some words and add whole verses. You'll also need to specifiy verse order, over all though Songselect has saved me MANY MANY hours of typing.